**Quantum Mechanics and Momentum**

Part 6: Time, Frequency, and Schrödinger’s Equation

Note that previously, we combined the deBroglie relation between momentum and (angular) wavenumber, the Fourier transform conversion between the position and wavenumber spaces, and the formula for the Fourier transform of a derivative to demonstrate (non-rigorously) that the momentum operator in the position basis is for a one-dimensional position space, and , where is here the gradient operator (see here), for a three-dimensional space.

Now, recall that just as we can perform a Fourier transform to change from position to the corresponding wavenumber space, a Fourier transform applied to a function of time returns a function of (angular) frequency:

(introduced here). We also have the deBroglie relation between energy and angular frequency *E*=ℏ*ω*. Thus, we should then expect some form of relation between the time derivative and the operator corresponding to energy; and there is. With the Hamiltonian operator, which is the operator for energy, we have for any time-varying wavefunction the relation . This is, in fact, the **time-dependent Schrödinger equation**. As the Hamiltonian is a linear operator with regards to the wavefunction, we see that the time-dependent Schrödinger equation is a linear differential equation, and that any linear combination of solutions is also a solution.

We see that the time-dependent Schrödinger equation is easily solved for wavefunctions of definite energy; from the nature of quantum operators for obervables, a wavefunction with definite energy *E*_{n} is an eigenfunction of the Hamiltonian with eigenvalue *E*_{n}. Then the time-dependent Schrödinger equation gives:

.

This is a basic separable first-order differential equation (in time), giving solution

, where *ψ*_{n}(*x*) is the spatial component of the wavefunction (which must be an eigenfunction of the Hamiltonian with eigenvalue *E*_{n}), and *ω*_{n} is the (angular) frequency corresponding to the energy *E*_{n} via the deBroglie relation *E*=ℏ*ω*.

(Note that the eigenvalue relation is the **time-independent Schrödinger equation**.)

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Tags: Differential Equation, Eigenvalue, Energy, Fourier Transform, Friday Physics, Hamiltonian, physics, Quantum Mechanics, Schrödinger Equation

This entry was posted on December 5, 2008 at 12:01 am and is filed under Math/Science. You can follow any responses to this entry through the RSS 2.0 feed.
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December 12, 2008 at 3:36 am |

[…] Friday 50 By twistedone151 Quantum Mechanics and Momentum Part 7: Plane Waves Last week, we introduced the time-dependent Schrödinger equation , and we noted that for an energy […]